infrared Spectra of Silicate-ions in Aqueous Solution

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چکیده

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Production of yttrium aluminum silicate microspheres by gelation of an aqueous solution containing yttrium and aluminum ions in silicone oil

Background: Radioactive yttrium glass microspheres are used for liver cancer treatment. These yttrium aluminum silicate microspheres are synthesized from yttrium, aluminum and silicone oxides by melting. There are two known processes used to transform irregular shaped glass particles into microspheres, these ‘spheroidization by flame’ and ‘spheroidization by gravitational fall...

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Interactions of silicate ions with zinc(II) and aluminum(III) in alkaline aqueous solution.

We present (29)Si, (27)Al, and (67)Zn NMR evidence to show that silicate ions in alkaline solution form complexes with zinc(II) (present as zincate, Zn(OH)(3)(-) or Zn(OH)(4)(2-)) and, concomitantly, with aluminate (Al(OH)(4)(-)). Zincate reacts with monomeric silicate at pH 14-15 to form [(HO)O(2)Si-O-Zn(OH)(3)](4-) and with dimeric silicate to produce [HO-SiO(2)-O-SiO(2)-O-Zn(OH)(3)](6-). The...

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Vibrational spectra of phosphate ions in aqueous solution probed by first-principles molecular dynamics.

We have carried out "first-principles" Born-Oppenheimer molecular dynamics (BOMD) simulations of the phosphate ions H₂PO₄⁻ and HPO₄²⁻ in liquid water and have calculated their IR spectra by Fourier transform techniques from the trajectories. IR bands were assigned by a so-called "generalized normal coordinate analysis". The effects of including Hartree-Fock (HF) exchange into the density functi...

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production of yttrium aluminum silicate microspheres by gelation of an aqueous solution containing yttrium and aluminum ions in silicone oil

background: radioactive yttrium glass microspheres are used for liver cancer treatment. these yttrium aluminum silicate microspheres are synthesized from yttrium, aluminum and silicone oxides by melting. there are two known processes used to transform irregular shaped glass particles into microspheres, these ‘spheroidization by flame’ and ‘spheroidization by gravitational fall in a tubular furn...

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Thermodynamic and kinetic properties of metal ions in aqueous solution

While it is evident that a metal ion in aqueous solution interacts electrostatically with water molecules and the anions present in the solution, it is equally apparent that often the metal ion chemically combines with varying numbers of ions or molecules to form complex species. This tendency towards coordination complexing is observed most often with the transition metals and results in a ser...

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ژورنال

عنوان ژورنال: Nippon kagaku zassi

سال: 1968

ISSN: 0369-5387,2185-0917

DOI: 10.1246/nikkashi1948.89.12_1217